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Performing the Marsh Test, 1856

Performing the Marsh Test, 1856. Doctor Alfred Swaine Taylor (left) and a colleague, performing the Marsh test on samples taken from the body of John Parsons Cook. The two were looking for traces of arsenic and antimony. The Marsh test is a method for the detection of minute amounts of arsenic in foods (the residue of fruit spray) or in stomach contents. The sample is placed in a flask with arsenic-free zinc and sulfuric acid. Arsine gas (also hydrogen) forms and is led through a drying tube to a hard glass tube in which it is heated. The arsenic is deposited as a "mirror" just beyond the heated area and on any cold surface held in the burning gas emanating from the jet. Antimony gives a similar test, but the deposit is insoluble in sodium hypochlorite, whereas arsenic will dissolve. The test was named for its inventor, the English chemist James Marsh.
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Performing the Marsh Test, 1856
Performing the Marsh Test, 1856. Doctor Alfred Swaine Taylor (left) and a colleague, performing the Marsh test on samples taken from the body of John Parsons Cook. The two were looking for traces of arsenic and antimony. The Marsh test is a method for the detection of minute amounts of arsenic in foods (the residue of fruit spray) or in stomach contents. The sample is placed in a flask with arsenic-free zinc and sulfuric acid. Arsine gas (also hydrogen) forms and is led through a drying tube to a hard glass tube in which it is heated. The arsenic is deposited as a "mirror" just beyond the heated area and on any cold surface held in the burning gas emanating from the jet. Antimony gives a similar test, but the deposit is insoluble in sodium hypochlorite, whereas arsenic will dissolve. The test was named for its inventor, the English chemist James Marsh.
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Album / NLM/Science Source
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3600 x 2802 px | 28.9 MB
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30.5 x 23.7 cm | 12.0 x 9.3 in (300 dpi)